Intercalation compounds of graphite*

نویسنده

  • M. S. Dresselhaus
چکیده

A broad review of recent research work on the preparation and the remarkable properties of intercalation compounds of graphite, covering a wide range of topics from the basic chemistry, physics and materials science to engineering applications.

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منابع مشابه

International Union of Pure and Applied Chemistry Inorganic Chemistry Division Commission on High Temperature and Solid State Chemistry* Nomenclature and Terminology of Graphite Intercalation Compounds

Recommendations are presented for the nomenclature and terminology of graphite intercalation compounds, i.e. compounds that retain the planarity of the layers in the graphite structure. Not included are compounds with covalent bonding of heteroatoms to the carbon atoms which leads to a sp3 hybridization of the carbon atoms and a corresponding loss of planarity of the layers. Rules for a structu...

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Van der Waals density functional study of the energetics of alkali metal intercalation in graphite

We report on the energetics of intercalation of lithium, sodium and potassium in graphite by density functional theory using recently developed van der Waals (vdW) density functionals. First stage intercalation compounds are well described by conventional functionals like GGA, but van der Waals functionals are crucial for higher stage intercalation compounds and graphite, where van der Waals in...

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Non-oxidative intercalation and exfoliation of graphite by Brønsted acids.

Graphite intercalation compounds are formed by inserting guest molecules or ions between sp(2)-bonded carbon layers. These compounds are interesting as synthetic metals and as precursors to graphene. For many decades it has been thought that graphite intercalation must involve host-guest charge transfer, resulting in partial oxidation, reduction or covalent modification of the graphene sheets. ...

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Nanotribological Properties of Graphite Intercalation Compounds: AFM Studies

Tetraalkylammonium salts have larger ions than metal ions, which can greatly change the interlayer space and energy, and then potentially tune the properties of graphite. In this work, various graphite intercalation compounds (GICs) have been synthesized by intercalating tetraoctylammonium bromide (TOAB) ions into graphite through electrochemical interactions under different reduction potential...

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Stable p- and n-type doping of few-layer graphene/graphite

ZnMg and NbCl5 were intercalated in graphite and the presence of such molecules between the graphene sheets results in nand p-type doping, respectively. The doping effect is confirmed by Hall and Raman measurements and the intercalation process is monitored by scanning tunneling microscopy. After intercalation the carrier concentration increase almost an order of magnitude and reaches values as...

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تاریخ انتشار 2002